Band structure of β-(BEDT-TTF) 2PF6. One-dimensional metal along the side-by-side molecular array

書誌事項

公開日
1985-02
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/0038-1098(85)90364-3
公開者
Elsevier BV

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説明

Abstract The energy-band structures of isostructural organic conductors, β-(BEDT-TTF) 2 PF 6 and (BEDT-TTF) 2 AsF 6 are calculated (BEDT-TTF: bis (ethylenedithio) tetrathiafulvalene). The strong dimerization of the face-to-face array makes the Fermi surface open perpendicularly to the side-by-side array. This dimer model indicates that the phase transition around room temperature is associated with a 2k F charge density wave.

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