Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation
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- Qianyan Zhang
- Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467-3860, United States
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- Katsuaki Kawasumi
- Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan
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- Yasutomo Segawa
- Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan
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- Kenichiro Itami
- Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan
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- Lawrence T. Scott
- Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467-3860, United States
書誌事項
- 公開日
- 2012-09-14
- DOI
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- 10.1021/ja306992k
- 公開者
- American Chemical Society (ACS)
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説明
All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 134 (38), 15664-15667, 2012-09-14
American Chemical Society (ACS)