Acceptorless Dehydrogenation of N‐Heterocycles by Merging Visible‐Light Photoredox Catalysis and Cobalt Catalysis
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- Ke‐Han He
- Center for Organic Chemistry Frontier Institute of Science and Technology Xi'an Jiaotong University Xi'an Shaanxi 710054 China
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- Fang‐Fang Tan
- Center for Organic Chemistry Frontier Institute of Science and Technology Xi'an Jiaotong University Xi'an Shaanxi 710054 China
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- Chao‐Zheng Zhou
- Center for Organic Chemistry Frontier Institute of Science and Technology Xi'an Jiaotong University Xi'an Shaanxi 710054 China
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- Gui‐Jiang Zhou
- Department of Chemistry School of Science Xi'an Jiaotong University Xi'an 710049 China
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- Xiao‐Long Yang
- Department of Chemistry School of Science Xi'an Jiaotong University Xi'an 710049 China
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- Yang Li
- Center for Organic Chemistry Frontier Institute of Science and Technology Xi'an Jiaotong University Xi'an Shaanxi 710054 China
書誌事項
- 公開日
- 2017-02-03
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.201612486
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Herein, the first acceptorless dehydrogenation of tetrahydroquinolines (THQs), indolines, and other related N‐heterocycles, by merging visible‐light photoredox catalysis and cobalt catalysis at ambient temperature, is described. The potential applications to organic transformations and hydrogen‐storage materials are demonstrated. Primary mechanistic investigations indicate that the catalytic cycle occurs predominantly by an oxidative quenching pathway.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 56 (11), 3080-3084, 2017-02-03
Wiley
