Heterogeneous Catalysis in Zeolites, Mesoporous Silica, and Metal–Organic Frameworks

  • Jie Liang
    Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University 21 Nanyang Link Singapore 637371 Singapore
  • Zibin Liang
    Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 China
  • Ruqiang Zou
    Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 China
  • Yanli Zhao
    Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University 21 Nanyang Link Singapore 637371 Singapore

書誌事項

公開日
2017-06-19
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201701139
公開者
Wiley

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説明

<jats:p>Crystalline porous materials are important in the development of catalytic systems with high scientific and industrial impact. Zeolites, ordered mesoporous silica, and metal–organic frameworks (MOFs) are three types of porous materials that can be used as heterogeneous catalysts. This review focuses on a comparison of the catalytic activities of zeolites, mesoporous silica, and MOFs. In the first part of the review, the distinctive properties of these porous materials relevant to catalysis are discussed, and the corresponding catalytic reactions are highlighted. In the second part, the catalytic behaviors of zeolites, mesoporous silica, and MOFs in four types of general organic reactions (acid, base, oxidation, and hydrogenation) are compared. The advantages and disadvantages of each porous material for catalytic reactions are summarized. Conclusions and prospects for future development of these porous materials in this field are provided in the last section. This review aims to highlight recent research advancements in zeolites, ordered mesoporous silica, and MOFs for heterogeneous catalysis, and inspire further studies in this rapidly developing field.</jats:p>

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