<i>In-situ</i> conductivity and Seebeck measurements of highly efficient n-dopants in fullerene C60

  • Torben Menke
    Technische Universität Dresden Institut für Angewandte Photophysik, , 01062 Dresden, Germany
  • Debdutta Ray
    Technische Universität Dresden Institut für Angewandte Photophysik, , 01062 Dresden, Germany
  • Jan Meiss
    Technische Universität Dresden Institut für Angewandte Photophysik, , 01062 Dresden, Germany
  • Karl Leo
    Technische Universität Dresden Institut für Angewandte Photophysik, , 01062 Dresden, Germany
  • Moritz Riede
    Technische Universität Dresden Institut für Angewandte Photophysik, , 01062 Dresden, Germany

書誌事項

公開日
2012-02-27
DOI
  • 10.1063/1.3689778
公開者
AIP Publishing

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説明

<jats:p>We present two organic dimetal complexes Cr2(hpp)4 and W2(hpp)4 as n-dopants investigated in the model system of fullerene C60 for the application in organic electronic devices. Conductivity and Seebeck measurements on doped layers are carried out in vacuum at different doping concentrations and various substrate temperatures to compare the two dopants. Very high conductivities of up to 4 S/cm are achieved for both organic dopants. The thermal activation energy of the conductivity as well as the measured Seebeck coefficient are found to decrease with increasing doping concentration, indicating a shift of the Fermi level towards the electron transport level of the n-doped C60.</jats:p>

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