Synthesis and Properties of Higher Homologues of Bis-Fused TTF

Yohji Misaki, Kazuya Kawakami, Natsuko Higuchi, Hiroyuki Nishikawa, Takeshi Miura, Tokio Yamabe

doi:10.1080/10587259608037936

Synthesis and Properties of Higher Homologues of Bis-Fused TTF

Yohji Misaki

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01
Kazuya Kawakami

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01
Natsuko Higuchi

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01
Hiroyuki Nishikawa

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01
Takeshi Miura

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01
Tokio Yamabe

a Division of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida, Kyoto , 606-01

説明

Abstract Several derivatives of higher homologues of bis-fused TTF, BDT-TTPY (1) and DT-TTP (2), have been synthesized. Cyclic voltammograms of 1 and 2consist of three-pairs of double-electron and five-pairs of single electron redox waves, respectively. Most of cation radical salts obtained by the chemical doping with appropriate oxidants showed relatively high conductivity ([sgrave]rt =10-2-101 S cm1 on compressed pellets).