The pulsed electron–electron double resonance and “2+1” electron spin echo study of the oriented oxygen-evolving and Mn-depleted preparations of photosystem II
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- Andrei V. Astashkin
- Faculty of Science, Kwansei Gakuin University, Nishinomiya 662, Japan
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- Hideyuki Hara
- Faculty of Science, Kwansei Gakuin University, Nishinomiya 662, Japan
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- Asako Kawamori
- Faculty of Science, Kwansei Gakuin University, Nishinomiya 662, Japan
説明
<jats:p>A “2+1” electron spin echo method has been applied to measure the angular orientation of the radius-vector RDZ joining the redox-active tyrosine residues YD and YZ in membrane-oriented Mn-depleted preparation of photosystem II. The angle between RDZ and the normal to the photosystem II membrane was determined to be 100°±2°, where the angle of 0° corresponds to the direction from YD towards the stromal side of the membrane, along the membrane normal. A pulsed electron–electron double resonance method has been used to obtain similar information for YD and Mn cluster in oriented sample of oxygen-evolving photosystem II. The angle between the radius-vector from YD to the Mn cluster, RDMn, and the membrane normal was found to be 110°±2°.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 108 (9), 3805-3812, 1998-03-01
AIP Publishing
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詳細情報 詳細情報について
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- CRID
- 1362262944375866880
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- DOI
- 10.1063/1.475770
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- ISSN
- 10897690
- 00219606
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- データソース種別
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- Crossref
- OpenAIRE