Novel κ‐type organic metal based on a bis‐fused tetrathiafulvalene derivative

Yohji Misaki, Takeshi Miura, Masateru Taniguchi, Hideki Fujiwara, Tokio Yamabe, Takehiko Mori, Hatsumi Mori, Shoji Tanaka

doi:10.1002/adma.19970090906

Novel κ‐type organic metal based on a bis‐fused tetrathiafulvalene derivative

説明

<jats:p><jats:bold>A novel</jats:bold> k‐type organic metal based on 4,5,‐cyclohexeno‐TTP (where TTP is bis‐fused tetrathiafulvalene, TTF), see Figure, is reported. The synthesis, structure, and electrical properties are described. It is suggested that, following this <jats:italic>demonstration</jats:italic> of a TTF‐based organic metal without a chalcogeno‐based substituent, further CH‐TTP salts should be investigated for conductivity and superconductivity.<jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/gif" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/must001.gif"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>