Organometallic conducting polymers synthesized by metallacycling polymerization

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<jats:title>Abstract</jats:title><jats:p>The study on the synthesis of π‐conjugated polymers using cobaltacyclopentadiene formation reaction of CpCo(PPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub> and conjugated diacetylene and the structure and physical properties of the polymers is overviewed. The substituents on the diacetylene affect crucially the solubility, the degree of polymerization, redox properties, and electronic structures and so on. Recent synthesis of a ruthenacyclopentatriene polymers by metallacyling polymerization is also described.</jats:p>

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