Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF<sub>3</sub>

Pavlo Nikolaienko, Roman Pluta, Magnus Rueping

doi:10.1002/chem.201402679

Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF<sub>3</sub>

DOI Web Site Web Site 被引用文献1件

書誌事項

公開日: 2014-07-14

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/chem.201402679

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>A direct process for the trifluoromethylthiolation of allylic and benzylic alcohols under mild conditions has been developed. A wide range of free alcohols underwent nucleophilic substitution in the presence of stable CuSCF<jats:sub>3</jats:sub> and BF<jats:sub>3</jats:sub><jats:bold>⋅</jats:bold>Et<jats:sub>2</jats:sub>O to give the corresponding products in good to excellent yields.</jats:p>