New synthetic reactions catalyzed by cobalt complexes

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  • Hideki Yorimitsu
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, 615-8510 Kyoto, Japan
  • Koichiro Oshima
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, 615-8510 Kyoto, Japan
  • 00372566
  • 00111922

書誌事項

公開日
2006-01-01
DOI
  • 10.1351/pac200678020441
  • 10.1002/chin.200631251
公開者
Walter de Gruyter GmbH

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<jats:title>Abstract</jats:title> <jats:p>Without suffering from β-elimination, cobalt complexes allow cross-coupling reactions of alkyl halides with Grignard reagents. A combination of a cobalt complex and trimethylsilylmethyl Grignard reagent effects Mizoroki-Heck-type reaction of alkyl halide with styrene, which conventional palladium catalysts have never made possible. Cobalt exhibits intriguing catalytic activities on hydrophosphination and allylzincation of alkynes. Silylmethylcobalt reagent is a powerful tool for the synthesis of highly silylated ethenes.</jats:p>

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