The Electronic Spectra of Cata-Condensed Hydrocarbons

  • William Moffitt
    Department of Chemistry, Harvard University, Cambridge, Massachusetts

書誌事項

公開日
1954-02-01
DOI
  • 10.1063/1.1740059
公開者
AIP Publishing

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説明

<jats:p>It is shown how the main features of the spectra of cata-condensed hydrocarbons may be explained on the basis of a very simple model. This, so-called perimeter model was used, in its free-electron variant, by Platt in order to classify the spectra. In this note, a more quantitative version is formulated which enables calculations to be made; it may be considered as an approximation either to an antisymmetrized molecular orbital treatment or to the method of atoms in molecules.</jats:p>

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