The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO<sub>2</sub>: a computational study
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- Lei Zhu
- School of Chemistry and Chemical Engineering
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- Jian-Heng Ye
- Key Laboratory of Green Chemistry & Technology of Ministry of Education
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- Meng Duan
- School of Chemistry and Chemical Engineering
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- Xiaotian Qi
- School of Chemistry and Chemical Engineering
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- Da-Gang Yu
- Key Laboratory of Green Chemistry & Technology of Ministry of Education
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- Ruopeng Bai
- School of Chemistry and Chemical Engineering
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- Yu Lan
- School of Chemistry and Chemical Engineering
書誌事項
- 公開日
- 2018
- 権利情報
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- http://rsc.li/journals-terms-of-use
- DOI
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- 10.1039/c7qo00838d
- 公開者
- Royal Society of Chemistry (RSC)
説明
<p>We propose a novel Cu(<sc>i</sc>)–Cu(<sc>ii</sc>) catalytic cycle for the copper-catalyzed oxytrifluoromethylation of allylamines with CO2, which proceeds through a radical–radical cross-coupling pathway.</p>
収録刊行物
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- Organic Chemistry Frontiers
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Organic Chemistry Frontiers 5 (4), 633-639, 2018
Royal Society of Chemistry (RSC)