Silicon‐Bridge Effects on Photophysical Properties of Silafluorenes

DOI HANDLE Web Site Web Site PubMed 研究データあり 被引用文献17件

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公開日
2008-09
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/asia.200800094
公開者
Wiley

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<jats:title>Abstract</jats:title><jats:p>The preparation of 4,5‐dimethylsilylene‐ or 4,5‐tetramethyldisilylene‐bridged 9‐silafluorenes was achieved by lithiation of 2,2′,6,6′‐tetrabromobiphenyls followed by silylation with dichlorodimethylsilane or 1,2‐dichloro‐1,1,2,2‐tetramethyldisilane, respectively. X‐ray analysis of the silylene‐bridged silafluorene revealed that the molecular framework was perfectly planar and four SiC(methyl) σ bonds were completely orthogonal to the plane. Both the silicon atoms and the benzene rings were significantly deformed from the normal tetrahedral and hexagon shapes, respectively. The silicon bridge at the 4,5‐positions was found to induce a red shift of the absorption and fluorescence spectra measured in cyclohexane, compared with 9‐silafluorenes. It is remarkable that the disilylene‐bridged silafluorene emitted blue light (<jats:italic>λ</jats:italic><jats:sub>em</jats:sub>=450 nm) with a large Stokes shift. The emission maxima of the silicon‐bridged silafluorenes in thin films were similar to those measured in cyclohexane solution. DFT calculations suggested that introduction of the silicon bridge led to increases in both the HOMO and LUMO levels compared with 9‐silafluorene.</jats:p>

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