Crystal structure of μ‐phenoxo bridged dicopper complex: {N‐[(2‐hydroxylato‐5‐methyl)benzyl‐(2′‐hydroxylato‐3′,5′‐dimethylbenzyl)]ethyl amine dicopper(II)}
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>The title compound crystallizes in monoclinic space group C2/c with cell parameters a = 21.404(2), b = 13.962(1), c = 17.917(1)Å, β = 124.394(2)°, V = 4418.3(6)Å<jats:sup>3</jats:sup>, Z = 8, D<jats:sub>cal</jats:sub> = 1.193Mg/m<jats:sup>3</jats:sup> and T = 293 K. The structure was solved by Patterson method and refined by full‐matrix least‐squares procedures to final R = 0.0882 using 5253 observed reflections. The tetra coordinated copper atom have a slight distorted square planar geometry with the Cu‐Cu distance of 2.987(1)Å. The two six membered rings containing copper atom assume distorted sofa conformation. C‐H…π and C‐H…O type of intermolecular interactions play a role in stabilizing the crystal packing in addition to van der Waals forces.</jats:p>
収録刊行物
-
- Crystal Research and Technology
-
Crystal Research and Technology 37 (12), 1360-1367, 2002-12
Wiley