Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis

William A. Donaldson, Subhabrata Chaudhury

doi:10.1002/ejoc.200900141

Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis

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書誌事項

公開日: 2009-07-27

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/ejoc.200900141

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Complexation of (tricarbonyl)iron to an acyclic diene serves to protect the ligand against oxidation, reduction, and cycloaddition reactions, whereas the steric bulk of this adjunct serves to direct the approaches of reagents to unsaturated groups attached to the diene onto the face opposite to iron. Furthermore, the Fe(CO)<jats:sub>3</jats:sub> moiety can serve to stabilize carbocation centers adjacent to the diene (i.e. pentadienyl‐iron cations). Recent applications of these reactivities to the synthesis of polyene‐, cyclopropane‐, cycloheptadiene‐, and cyclohexenone‐containing natural products or analogues are presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)</jats:p>