Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β‐Cyclodextrin Dimers

書誌事項

公開日
2015-06-18
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/anie.201503614
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>A photochemically interconvertible supramolecular nanotube–nanoparticle system was constructed through secondary assembling of self‐aggregates of amphiphilic porphyrin derivatives mediated by <jats:italic>trans</jats:italic>‐ and <jats:italic>cis</jats:italic>‐azobenzene‐bridged bis(permethyl‐β‐cyclodextrin). Significantly, these nanotubes and nanoparticles were able to interconvert upon irradiation at different wavelengths, and this photocontrolled morphological conversion is reversible and recyclable for tens of times, which will provide a feasible and convenient way to construct the ordered nanostructure with various morphologies that can be smartly controlled by the environmentally benign external stimulus.</jats:p>

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