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- Sakiat Hossain
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
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- Yoshiki Niihori
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
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- Lakshmi V. Nair
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
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- Bharat Kumar
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
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- Yuichi Negishi
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
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- Wataru Kurashige
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1−3 Kagurazaka, Shinjuku-ku, Tokyo 162−8601, Japan
書誌事項
- 公開日
- 2018-11-21
- DOI
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- 10.1021/acs.accounts.8b00453
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Metal alloys exhibit functionalities unlike those of single metals. Such alloying has drawn considerable research interest, particularly for nanoscale particles (metal clusters/nanoparticles), from the viewpoint of creating new functional nanomaterials. In gas phase cluster research, generated alloy clusters can be spatially separated with atomic precision in vacuum. Thus, the influences of increases or decreases in each element on the overall electronic structure of the cluster can be elucidated. However, to further understand the related mixing and synergistic effects, alloy clusters need to be produced on a large scale and characterized by various techniques. Because alloy clusters protected by thiolate (SR) can be synthesized by chemical methods and are stable in both solution and the solid state, these clusters are ideal study materials to better understand the mixing and synergistic effects. Moreover, the alloy clusters thus created have potential applications as functional materials. Therefore, since 2008, we have been working on establishing a precise synthesis method for SR-protected alloy clusters and elucidating their mixing and synergistic effects. Early research focused on the precise synthesis of alloy clusters wherein some of the Au in the stable SR-protected gold clusters ([Au
収録刊行物
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- Accounts of Chemical Research
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Accounts of Chemical Research 51 (12), 3114-3124, 2018-11-21
American Chemical Society (ACS)
