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- A. De Wit
- Nonlinear Physical Chemistry Unit, Université Libre de Bruxelles, 1050 Brussels, Belgium;
説明
<jats:p> By modifying a physical property of a solution like its density or viscosity, chemical reactions can modify and even trigger convective flows. These flows in turn affect the spatiotemporal distribution of the chemical species. A nontrivial coupling between reactions and flows then occurs. We present simple model systems of this chemo-hydrodynamic coupling. In particular, we illustrate the possibility of chemical reactions controlling or triggering viscous fingering, Rayleigh–Taylor, double-diffusive, and convective dissolution instabilities. We discuss laboratory experiments performed to study these phenomena and compare the experimental results to theoretical predictions. In each case we contrast the chemo-hydrodynamic patterns and instabilities with those that develop in nonreactive systems and unify the different dynamics in terms of the common features of the related spatial mobility profiles. </jats:p>
収録刊行物
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- Annual Review of Fluid Mechanics
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Annual Review of Fluid Mechanics 52 (1), 531-555, 2020-01-05
Annual Reviews