Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes

DOI PDF 被引用文献8件
  • Hiroto Yoshida
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University
  • Yuki Takemoto
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University
  • Ken Takaki
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University

書誌事項

公開日
2014-10-29
DOI
  • 10.1055/s-0034-1379385
公開者
Georg Thieme Verlag KG

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説明

A copper complex has been found to catalyze the borylstannylation of alkenes through three-component coupling with a diboron and a tin alkoxide, affording vic-borylstannylalkanes of structural diversity in a regio- and stereoselective manner. The versatility of this borylstannylation has been also demonstrated by employing allenes, leading to the sole formation of borylstannylated products, which have alkenylborane and allylstannane units.

収録刊行物

  • Synthesis

    Synthesis 46 (22), 3024-3032, 2014-10-29

    Georg Thieme Verlag KG

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