High resolution NMR studies on sequence distribution of vinylidene chloride copolymers

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<jats:title>Abstract</jats:title><jats:p>Sequence distributions of several radical copolymers of vinylidene chloride were examined by NMR spectroscopy, including methyl methacrylate, benzyl methacrylate, methaeryloyl chloride, methyl acrylate, α‐methylstyrene, styrene, and vinyl acetate as comonomers. Except for the α‐methylstyrene and styrene systems, some of the diad, triad, and tetrad sequences were observed in the CH<jats:sub>2</jats:sub> and αCH<jats:sub>3</jats:sub> resonances and are discussed in the light of the usual copolymerization theory.</jats:p>

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