Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene

  • B. Wolter
    ICFO–Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.
  • M. G. Pullen
    ICFO–Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.
  • A.-T. Le
    J. R. Macdonald Laboratory, Physics Department, Kansas State University, Manhattan, KS 66506-2604, USA.
  • M. Baudisch
    ICFO–Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.
  • K. Doblhoff-Dier
    Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, Post Office Box 9502, 2300 RA Leiden, Netherlands.
  • A. Senftleben
    Universität Kassel, Institut für Physik und CINSaT, Heinrich-Plett-Str. 40, 34132 Kassel, Germany.
  • M. Hemmer
    ICFO–Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.
  • C. D. Schröter
    Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany.
  • J. Ullrich
    Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany.
  • T. Pfeifer
    Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany.
  • R. Moshammer
    Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany.
  • S. Gräfe
    Institute for Physical Chemistry, Friedrich-Schiller University Jena, 07743 Jena, Germany.
  • O. Vendrell
    Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron (DESY), Centre for Ultrafast Imaging (CUI), 22607 Hamburg, Germany.
  • C. D. Lin
    J. R. Macdonald Laboratory, Physics Department, Kansas State University, Manhattan, KS 66506-2604, USA.
  • J. Biegert
    ICFO–Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.

書誌事項

公開日
2016-10-21
権利情報
  • http://www.sciencemag.org/about/science-licenses-journal-article-reuse
DOI
  • 10.1126/science.aah3429
公開者
American Association for the Advancement of Science (AAAS)

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説明

<jats:title>Acetylene's scission visualized by selfie</jats:title> <jats:p> Can molecules take pictures of themselves? That is more or less the principle underlying laser-induced electron diffraction (LIED): A laser field strips an electron from a molecule and then sends it back to report on the structure of the remaining ion. Wolter <jats:italic>et al.</jats:italic> applied this technique to acetylene to track the cleavage of its C–H bond after double ionization (see the Perspective by Ruan). They imaged the full structure of the molecule and also distinguished more rapid dissociative dynamics when it was oriented parallel rather than perpendicular to the LIED field. </jats:p> <jats:p> <jats:italic>Science</jats:italic> , this issue p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6310" page="308" related-article-type="in-this-issue" vol="354" xlink:href="10.1126/science.aah3429">308</jats:related-article> ; see also p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6310" page="283" related-article-type="in-this-issue" vol="354" xlink:href="10.1126/science.aai8656">283</jats:related-article> </jats:p>

収録刊行物

  • Science

    Science 354 (6310), 308-312, 2016-10-21

    American Association for the Advancement of Science (AAAS)

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