Hierarchical Assembly of Ultranarrow Alkylamine-Coated ZnS Nanorods: A Synchrotron Surface X-Ray Diffraction Study

  • Nataly Belman
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Somobrata Acharya
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Oleg Konovalov
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Alexei Vorobiev
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Jacob Israelachvili
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Shlomo Efrima
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...
  • Yuval Golan
    Department of Materials Engineering, Department of Chemistry, Ilse Katz Institute of Nanotechnology, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan, European Synchrotron Radiation Facility, Beamline ID-10B, BP 220, 38043 Grenoble, France, and Department of Chemical Engineering, Materials Department and...

書誌事項

公開日
2008-09-30
DOI
  • 10.1021/nl802287h
公開者
American Chemical Society (ACS)

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説明

The packing of anisotropic ultranarrow nanoparticles ( r <or= 0.5 nm) in Langmuir films was investigated for two types of nanoparticles: short ZnS wires coated with tetradecylamine and ZnS rods coated with octadecylamine. In situ grazing incidence small-angle X-ray scattering (GISAXS) revealed the formation, even under zero pressure, of ordered superstructures on the water surface consisting of alternating nanoparticles. A hierarchical "packing model" is proposed, based on GISAXS, transmission electron microscopy, thermogravimetric analysis, and grazing incidence X-ray diffraction of pure surfactant Langmuir films.

収録刊行物

  • Nano Letters

    Nano Letters 8 (11), 3858-3864, 2008-09-30

    American Chemical Society (ACS)

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