A Permselective CeO<sub><i>x</i></sub> Coating To Improve the Stability of Oxygen Evolution Electrocatalysts
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- Keisuke Obata
- King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC) and Physical Sciences and Engineering Division (PSE) 4700 KAUST Thuwal 23955-6900 Saudi Arabia
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- Kazuhiro Takanabe
- King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC) and Physical Sciences and Engineering Division (PSE) 4700 KAUST Thuwal 23955-6900 Saudi Arabia
書誌事項
- 公開日
- 2018-01-05
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.201712121
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Highly active NiFeO<jats:sub><jats:italic>x</jats:italic></jats:sub> electrocatalysts for the oxygen evolution reaction (OER) suffer gradual deactivation with time owing to the loss of Fe species from the active sites into solution during catalysis. The anodic deposition of a CeO<jats:sub><jats:italic>x</jats:italic></jats:sub> layer prevents the loss of such Fe species from the OER catalysts, achieving a highly stable performance. The CeO<jats:sub><jats:italic>x</jats:italic></jats:sub> layer does not affect the OER activity of the catalyst underneath but exhibits unique permselectivity, allowing the permeation of OH<jats:sup>−</jats:sup> and O<jats:sub>2</jats:sub> through while preventing the diffusion of redox ions through the layer to function as a selective O<jats:sub>2</jats:sub>‐evolving electrode. The use of such a permselective protective layer provides a new strategy for improving the durability of electrocatalysts.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 57 (6), 1616-1620, 2018-01-05
Wiley
