Solid-Phase Extraction, Separation, and Visible Spectrophotometric Determination of Trace Amounts of Iron in Water Samples
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- Yadollah Yamini
- Tarbiat Modarres University, Department of Chemistry, Tehran, Iran
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- Nayyereh Amiri
- Tarbiat Modarres University, Department of Chemistry, Tehran, Iran
書誌事項
- 公開日
- 2001-05-01
- 権利情報
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- https://academic.oup.com/journals/pages/open_access/funder_policies/chorus/standard_publication_model
- DOI
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- 10.1093/jaoac/84.3.713
- 公開者
- Oxford University Press (OUP)
この論文をさがす
説明
<jats:title>Abstract</jats:title> <jats:p>A simple and reliable method is presented for the rapid extraction, separation, preconcentration, and determination of iron as its bathophenanthroline complex by the use of octadecylsilica membrane disks and spectrophotometry. We evaluted extraction efficiency, the influence of sample matrix, type and optimum amount of extractant, flow rates of sample solution and eluent, pH, amounts of bathophenanthroline and hydroxylamine hydrochloride, breakthrough volume, and limit of detection. We also studied the effects of various cationic interferences on percent recovery of iron. Complete elution of the complex from disks was obtained with a minimal amount of solvent. The limit of detection of the proposed method is 0.080 ppb. The method was applied to the recovery and determination of iron in natural waters.</jats:p>
収録刊行物
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- Journal of AOAC INTERNATIONAL
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Journal of AOAC INTERNATIONAL 84 (3), 713-718, 2001-05-01
Oxford University Press (OUP)