Influence of casting and curing conditions on gas sorption and transport in polyimide films

書誌事項

公開日
1987-02
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/pen.760270306
公開者
Wiley

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説明

<jats:title>Abstract</jats:title> <jats:p> Carbon dioxide and methane gas permeabilities, solubilities and diffusivities for poly [N, N′‐(phenoxyphenyl)‐pyromellitimide] films synthesized in our laboratory are contrasted with values measured for a chemically identical commercial polyimide film, Kapton H. The synthesized samples exhibited greater permeabilities, solubilities, and diffusivitles than those of the commercial sample. At the same time, the higher carbon dioxide permeability is associated with only a moderate reduction in permselectivity for the CO <jats:sub>2</jats:sub> /CH <jats:sub>4</jats:sub> system. The increased sorption and transport coefficients for the synthesized sample are attributed to a lower degree of aggregation and orientation of this film as compared to the Kapton H sample. </jats:p>

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