A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides

  • Ali Zavabeti
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Jian Zhen Ou
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Benjamin J. Carey
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Nitu Syed
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Rebecca Orrell-Trigg
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Edwin L. H. Mayes
    School of Applied Sciences, RMIT University, Melbourne, Victoria 3001, Australia.
  • Chenglong Xu
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Omid Kavehei
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Anthony P. O’Mullane
    School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, Queensland 4001, Australia.
  • Richard B. Kaner
    Department of Chemistry and Biochemistry, Department of Materials Science and Engineering, and California NanoSystems Institute, University of California, Los Angeles, CA 90095, USA.
  • Kourosh Kalantar-zadeh
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
  • Torben Daeneke
    School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.

説明

<jats:title>Expanding the world of 2D materials</jats:title> <jats:p> Two-dimensional (2D) materials have a wide variety of potential applications in the electronics industry. However, certain compositions of 2D materials are difficult to obtain owing to the challenges in exfoliating thin sheets from bulk crystals. Zavabeti <jats:italic>et al.</jats:italic> exploited liquid metals to synthesize 2D Ga <jats:sub>2</jats:sub> O <jats:sub>3</jats:sub> , HfO <jats:sub>2</jats:sub> , Gd <jats:sub>2</jats:sub> O <jats:sub>3</jats:sub> , and Al <jats:sub>2</jats:sub> O <jats:sub>3</jats:sub> . The 2D sheets appear as a surface layer in gallium-based liquid metals after the Hf, Gd, or Al is dissolved into the bulk alloy. The 2D oxide that appears on the surface is the oxide with the lowest energy, suggesting that it should be possible to make other 2D oxides by using the same process. </jats:p> <jats:p> <jats:italic>Science</jats:italic> , this issue p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6361" page="332" related-article-type="in-this-issue" vol="358" xlink:href="10.1126/science.aao4249">332</jats:related-article> </jats:p>

収録刊行物

  • Science

    Science 358 (6361), 332-335, 2017-10-20

    American Association for the Advancement of Science (AAAS)

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