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- Tim Bleith
- Anorganisch-Chemisches Institut Universität Heidelberg Im Neuenheimer Feld 270 69120 Heidelberg Germany
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- Qing‐Hai Deng
- Anorganisch-Chemisches Institut Universität Heidelberg Im Neuenheimer Feld 270 69120 Heidelberg Germany
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- Hubert Wadepohl
- Anorganisch-Chemisches Institut Universität Heidelberg Im Neuenheimer Feld 270 69120 Heidelberg Germany
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- Lutz H. Gade
- Anorganisch-Chemisches Institut Universität Heidelberg Im Neuenheimer Feld 270 69120 Heidelberg Germany
書誌事項
- 公開日
- 2016-06-02
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.201603072
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Whereas the stereochemical rigidity of the coordination sphere of boxmi/Cu<jats:sup>II</jats:sup> catalysts is key to achieving high enantioselectivity in the electrophilic alkylation of β‐ketoesters, this pathway is outperformed by a radical process for the corresponding catalytic transformation of oxindoles, giving rise to racemic products. For the corresponding Zn<jats:sup>II</jats:sup> catalysts, the selectivity in the latter process is outstanding despite the greater plasticity of the coordination shell. This reaction was thus developed into a highly useful synthetic method, which enabled the conversion of wide range of substrates with high yields and enantioselectivities.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 55 (27), 7852-7856, 2016-06-02
Wiley