High storage capacity and separation selectivity for C<sub>2</sub> hydrocarbons over methane in the metal–organic framework Cu–TDPAT

DOI Web Site 被引用文献1件
  • Kang Liu
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
  • Dingxuan Ma
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
  • Baiyan Li
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
  • Yi Li
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
  • Kexin Yao
    Advanced Membranes and Porous Materials Center
  • Zhijuan Zhang
    Institute of Atmospheric Environment Safety and Pollution Control
  • Yu Han
    Advanced Membranes and Porous Materials Center
  • Zhan Shi
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

書誌事項

公開日
2014
DOI
  • 10.1039/c4ta03656e
公開者
Royal Society of Chemistry (RSC)

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説明

<p>We report an <italic>rht</italic>-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C2 hydrocarbons and excellent selectivity over CH4. This MOF displays the highest reported C2H2–CH4 selectivity of 127.1 as well as a record high value for C2H4 adsorption enthalpy (49.5 kJ mol−1).</p>

収録刊行物

  • J. Mater. Chem. A

    J. Mater. Chem. A 2 (38), 15823-15828, 2014

    Royal Society of Chemistry (RSC)

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