Contiguous stereogenic quaternary carbons: A daunting challenge in natural products synthesis

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<jats:p> One element of structure that invariably increases the difficulty of a chemical synthesis is the presence in the target molecule of contiguous all-carbon quaternary stereocenters. This <jats:italic>Perspective</jats:italic> will examine the most useful transformations and strategies devised recently for directly assembling this structural unit. </jats:p>

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