Electroconductive Porous Coordination Polymer Cu[Cu(pdt)<sub>2</sub>] Composed of Donor and Acceptor Building Units
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- Shinya Takaishi
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan
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- Miyuki Hosoda
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan
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- Takashi Kajiwara
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan
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- Hitoshi Miyasaka
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan
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- Masahiro Yamashita
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan
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- Yasuyuki Nakanishi
- Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan
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- Yasutaka Kitagawa
- Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan
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- Kizashi Yamaguchi
- Center for Quantum Science and Technology under Extreme Conditions, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531, Japan
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- Atsushi Kobayashi
- Graduate School of Science, Kyushu University, 6-10-1 Hakozaki, Higashi, Fukuoka 812-8581, Japan
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- Hiroshi Kitagawa
- Graduate School of Science, Kyushu University, 6-10-1 Hakozaki, Higashi, Fukuoka 812-8581, Japan
書誌事項
- 公開日
- 2008-12-09
- DOI
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- 10.1021/ic802117q
- 公開者
- American Chemical Society (ACS)
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説明
We synthesized a new porous coordination polymer Cu[Cu(pdt)2], which shows relatively high electrical conductivity (6 x 10(-4) S cm(-1) at 300 K) by the introduction of electron donors and acceptors as building units. This compound is applicable as a porous electrode with high power density. In addition, this compound forms a triangular spin lattice and shows spin frustration.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 48 (19), 9048-9050, 2008-12-09
American Chemical Society (ACS)
