Influence of the electrode work function on the energy level alignment at organic-organic interfaces

  • Slawomir Braun
    Linköping University Department of Physics, Chemistry and Biology-IFM, , S-581 83 Linköping, Sweden
  • Michel P. de Jong
    Linköping University Department of Physics, Chemistry and Biology-IFM, , S-581 83 Linköping, Sweden
  • Wojciech Osikowicz
    Linköping University Department of Physics, Chemistry and Biology-IFM, , S-581 83 Linköping, Sweden
  • William R. Salaneck
    Linköping University Department of Physics, Chemistry and Biology-IFM, , S-581 83 Linköping, Sweden

書誌事項

公開日
2007-11-12
DOI
  • 10.1063/1.2806938
公開者
AIP Publishing

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説明

<jats:p>The energy level alignment at interfaces, in stacks comprising of (4,4′-N,N′-dicarbazolyl-biphenyl) (CBP), (4,4,4″-tris[3-methyl-phenyl(phenyl)amino]-triphenylamine) (m-MTDATA), and a conductive substrate, has been studied. We show that the alignment of energy levels depends on the equilibration of the chemical potential throughout the layer stack, while any electronic coupling between the individual layers is of lesser importance. This behavior is expected to occur for a broad class of weakly interacting interfaces and can have profound consequences for the design of organic electronic devices.</jats:p>

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