Recent Development on Cp*Ir(III)‐Catalyzed C−H Bond Functionalization
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- Xianwei Li
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
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- Wensen Ouyang
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
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- Jianhong Nie
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
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- Shaomin Ji
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
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- Qian Chen
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
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- Yanping Huo
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
書誌事項
- 公開日
- 2020-01-23
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/cctc.201902150
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Selective functionalization of ubiquitous C−H bonds of molecules would provide novel retrosynthetic insights and powerful tools for the rapid construction of molecular complexity. In this context, Cp*Ir(III) complexes have exhibited versatile reactivity towards the selective conversion of C−H bonds, with key features that include the use of readily transformable raw materials, great selectivity (chemo‐, stereo‐ and regio‐), high efficiency, mild reaction conditions and they enable late‐stage modification of complex molecules. Recently, Cp*Ir(III) catalysis has achieved a broad range of reactions such as multiple dehydrogenations and stereoselective C−X bond formations. These advancements are valuable to organometallic chemists and enable the efficient synthesis of functionalized architectures.</jats:p>
収録刊行物
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- ChemCatChem
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ChemCatChem 12 (9), 2358-2384, 2020-01-23
Wiley
