Recent Development on Cp*Ir(III)‐Catalyzed C−H Bond Functionalization

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  • Xianwei Li
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
  • Wensen Ouyang
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
  • Jianhong Nie
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
  • Shaomin Ji
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
  • Qian Chen
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
  • Yanping Huo
    School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China

Bibliographic Information

Published
2020-01-23
Rights Information
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/cctc.201902150
Publisher
Wiley

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Description

<jats:title>Abstract</jats:title><jats:p>Selective functionalization of ubiquitous C−H bonds of molecules would provide novel retrosynthetic insights and powerful tools for the rapid construction of molecular complexity. In this context, Cp*Ir(III) complexes have exhibited versatile reactivity towards the selective conversion of C−H bonds, with key features that include the use of readily transformable raw materials, great selectivity (chemo‐, stereo‐ and regio‐), high efficiency, mild reaction conditions and they enable late‐stage modification of complex molecules. Recently, Cp*Ir(III) catalysis has achieved a broad range of reactions such as multiple dehydrogenations and stereoselective C−X bond formations. These advancements are valuable to organometallic chemists and enable the efficient synthesis of functionalized architectures.</jats:p>

Journal

  • ChemCatChem

    ChemCatChem 12 (9), 2358-2384, 2020-01-23

    Wiley

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