Orientation dependence of the ferroelectric and piezoelectric behavior of Ba(Ti1−xZrx)O3 single crystals

  • Zhi Yu
    Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802
  • Ruyan Guo
    Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802
  • A. S. Bhalla
    Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802

書誌事項

公開日
2000-09-04
DOI
  • 10.1063/1.1308276
公開者
AIP Publishing

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説明

<jats:p>The dielectric properties, ferroelectric polarization, and piezoelectric strain behavior of Ba(Ti1−xZrx)O3 (x=0.05 and 0.08) single crystals are studied for different crystal orientations. The study of dielectric properties suggests that the three phase transitions in BaTiO3 are pinched by substituting Ti with Zr but the anisotropic dielectric behavior is present in crystals of various orientations. The remnant polarization and strain behavior are also studied for different crystal directions. Higher strain and lower polarization are obtained along the pseudocubic 〈001〉 direction compared to those observed along the 〈110〉 and 〈111〉 directions in both orthorhombic (x=0.05) and rhombohedral (x=0.08) phase. The results for the 〈001〉 oriented orthorhombic crystals with x=0.05 indicate the highest strain level (∼0.25%) with almost hysteresis-free behavior and high piezoelectric coefficient (d33=500 pC/N).</jats:p>

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