Chelating of Titanium by Lactic Acid in the Water-Soluble Diammonium Tris(2-hydroxypropionato)titanate(IV)
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- M. Kakihana
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
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- K. Tomita
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
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- V. Petrykin
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
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- M. Tada
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
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- S. Sasaki
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
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- Y. Nakamura
- Institute of Multidisciplinary Research and Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan, and Materials and Structures Laboratory and Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan
書誌事項
- 公開日
- 2004-06-25
- DOI
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- 10.1021/ic040031l
- 公開者
- American Chemical Society (ACS)
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説明
Stable water-soluble diammonium tris(2-hydroxypropionato)titanate(IV) [ammonium trilactatotitanate(IV)], (NH4)2[Ti(C3H4O3)3], was prepared in the crystalline form. According to the X-ray single-crystal diffraction data, this compound crystallizes in the cubic cell with a = 11.649(4) angstroms, space group P2(1)3 (no. 198), and has Z = 4 molecules per unit cell. The 13C NMR data and Raman and IR spectra support the determined structure. The absence of nonbonded functional groups restricts the formation of oligomers in contrast to the reported speciation of citratoperoxotitanate(IV) complexes.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 43 (15), 4546-4548, 2004-06-25
American Chemical Society (ACS)