Dynamic Self-Assembly Induced Rapid Dissolution of Cellulose at Low Temperatures

DOI Web Site 被引用文献4件
  • Jie Cai
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Lina Zhang
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Shilin Liu
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Yating Liu
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Xiaojuan Xu
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Xuming Chen
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Benjamin Chu
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Xinglin Guo
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Jian Xu
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • He Cheng
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Charles C. Han
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
  • Shigenori Kuga
    Department of Chemistry, Wuhan University, Wuhan 430072, China; Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; and Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan

書誌事項

公開日
2008-11-06
DOI
  • 10.1021/ma801110g
公開者
American Chemical Society (ACS)

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説明

Cellulose can be dissolved in precooled (−12 °C) 7 wt % NaOH−12 wt % urea aqueous solution within 2 min. This interesting process, to our knowledge, represents the most rapid dissolution of native cellulose. The results from 13C NMR, 15N NMR, 1H NMR, FT-IR, small-angle neutron scattering (SANS), transmission electron microscopy (TEM), and wide-angle X-ray diffraction (WAXD) suggested that NaOH “hydrates” could be more easily attracted to cellulose chains through the formation of new hydrogen-bonded networks at low temperatures, while the urea hydrates could not be associated directly with cellulose. However, the urea hydrates could possibly be self-assembled at the surface of the NaOH hydrogen-bonded cellulose to form an inclusion complex (IC), leading to the dissolution of cellulose. Scattering experiments, including dynamic and static light scattering, indicated that most cellulose molecules, with limited amounts of aggregation, could exist as extended rigid chains in dilute solution. Further, the cellu...

収録刊行物

  • Macromolecules

    Macromolecules 41 (23), 9345-9351, 2008-11-06

    American Chemical Society (ACS)

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