Thermodynamic Properties of the Group IA Elements

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  • C. B. Alcock
    Center for Sensor Materials, University of Notre Dame, Notre Dame, IN 46556
  • M. W. Chase
    Standard Reference Data Program, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-001
  • V. P. Itkin
    Department of Metallurgy and Materials Science, University of Toronto, Toronto, Ontario, M5S 1A4, Canada

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<jats:p>This review describes thermodynamic properties of condensed phases of the alkali metals, excluding francium for which the amount of information is too limited. The properties considered are: heat capacities from 0 to 1600 K, temperatures and enthalpies of fusion and martensitic transformation in Li and Na; discussion on the Debye temperature and electronic heat capacity coefficient at absolute zero temperature is also included. The paper is the second part of a series. Similar to our previous assessment of the II A group, this paper considers original studies, especially with respect to factors which influence the accuracy and reliability of results. Recommendations derived from such analyses are compared with most advanced previous reviews made at the Institute for High Temperatures (Moscow) and the National Institute of Standards and Technology (Washington). The properties of individual elements of the group are compared and suggestions are made for experimental studies which should improve poorly measured quantities. The review is supplemented by an IBM PC database which contains references, assessed data, brief description of studies, and has facilities for fitting and plotting of data and for adding new information. §</jats:p>

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