Volumes of aqueous hydrogen and hydroxide ions at 0 to 200 °C

  • Yizhak Marcus
    Hebrew University of Jerusalem Institute of Chemistry, , Jerusalem 91904, Israel

書誌事項

公開日
2012-10-17
DOI
  • 10.1063/1.4758071
公開者
AIP Publishing

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説明

<jats:p>The electrostriction of aqueous hydrogen and hydroxide ions at infinite dilution was calculated by the shell-by-shell method over the temperature range 0 to 200 °C. The calculation required an estimate of the ionic radius of these ions, and comparison with data for aqueous lithium, sodium, and fluoride ions provided values for the nominal sizes of the hydrogen and hydroxide ions in solution. From the volumetric standpoint, these sizes are surprisingly smaller than the size of a water molecule.</jats:p>

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