Dinuclear Ruthenium(II) κ<sup>2</sup>-Diamido/η<sup>6</sup>-Naphthalene Complexes Featuring a Coordinatively Unsaturated yet Highly π-Basic (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ru Diamide Fragment

DOI Web Site 研究データあり 被引用文献6件
  • Shin Takemoto
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan, and Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
  • Shinya Oshio
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan, and Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
  • Takayuki Shiromoto
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan, and Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
  • Hiroyuki Matsuzaka
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan, and Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan

書誌事項

公開日
2005-02-01
DOI
  • 10.1021/om049274b
公開者
American Chemical Society (ACS)

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説明

Acetonitrile induces a clean isomerization of the amido-bridged diruthenium complex [(Cp*Ru)2{μ2-κ2:η4-2,3-naphthalenediamido}] (1) into the κ2:η6-bonded dinuclear complex [Cp*Ru{μ2-κ2:η6-2,3-naphthalenediamido}RuCp*] (2a), featuring a coordinatively unsaturated Cp*Ru terminal diamide fragment. Structural and spectroscopic data of its carbon monoxide and tert-butyl isocyanide adducts indicate that the Cp*Ru diamide fragment can serve as a strong π-base.

収録刊行物

  • Organometallics

    Organometallics 24 (5), 801-804, 2005-02-01

    American Chemical Society (ACS)

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