Modification at a boron unit: tuning electronic and optical properties of π-conjugated acyclic anion receptors

書誌事項

公開日
2010
DOI
  • 10.1039/c0ob00044b
公開者
Royal Society of Chemistry (RSC)

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説明

Substituents at the boron unit of dipyrrolyldiketone boron complexes as pi-conjugated acyclic anion receptors play crucial roles for the tuning of solid-state molecular assemblies, anion-binding behaviour and electronic and optical properties. In particular, emission quantum yields can be significantly tunable by boron substituents and pyrrole alpha-aryl moieties.

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