Silver(I) Coordination Polymer of 2,5-Bis- (4‘,5‘-bis(methylthio)-1‘,3‘-dithiol-2‘-ylidene)- 1,3,4,6-tetrathiapentalene (TTM-TTP) and Its Highly Conductive Iodine Derivative
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- Jian Chu Zhong
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Yohji Misaki
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Megumu Munakata
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Takayoshi Kuroda-Sowa
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Masahiko Maekawa
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Yusaku Suenaga
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
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- Hisashi Konaka
- Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka, Osaka 577-8502, Japan, and Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan
Description
The novel silver(I) coordination polymer with 2,5-bis(4‘,5‘-bis(methylthio)-1‘,3‘-dithiol-2‘ylidene)-1,3,4,6-tetrathiapentalene (TTM-TTP), [Ag(TTM-TTP)(CF3SO3)]n (1), which consists of 1-D waving chains, was synthesized and characterized. Polymer 1 can be also regarded as a 3-D supramolecular network formed via many shorter side-by-side and face-to-face S···S contacts. This polymer and its iodine-doped compound 2 behave as semiconductors with σ25°C values of 7.1 × 10-6 and 0.85 S cm-1, respectively.
Journal
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- Inorganic Chemistry
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Inorganic Chemistry 40 (27), 7096-7098, 2001-11-27
American Chemical Society (ACS)
