抄録
<jats:title>Abstract</jats:title><jats:p>The reaction of living polystyrene, prepared with butyllithium as an initiator in a tetrahydrofuran/benzene (vol. ratio 1/1 or 2/1) solution at −30°C or −50°C, with chlorodimethylvinylsilane was carried out to prepare polystyrene with narrow molecular‐weight distribution and with a vinylsilane end group (<jats:bold>1</jats:bold>). The radical copolymerization of vinyl acetate with <jats:bold>1</jats:bold> in ethyl acetate solution yields poly(vinyl acetate)‐<jats:italic>graft</jats:italic>‐polystyrene (<jats:bold>2</jats:bold>) of controlled graft segement length. The subsequent saponification of <jats:bold>2</jats:bold> with NaOH in methanol provides poly(vinyl alcohol)‐<jats:italic>graft</jats:italic>‐polystyrene (<jats:bold>3</jats:bold>).</jats:p>
収録刊行物
-
- Die Makromolekulare Chemie
-
Die Makromolekulare Chemie 194 (10), 2827-2837, 1993-10
Wiley