Enantioselective Synthesis of Herbarumin III by Using a Chelation‐Controlled Reduction

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<jats:title>Abstract</jats:title><jats:p>The total synthesis of herbarumin III (<jats:bold>1</jats:bold>) was achieved <jats:italic>via</jats:italic> an alkynide ion addition onto a chiral aldehyde and LiAlH<jats:sub>4</jats:sub>/LiI reduction as key steps (<jats:italic>Scheme 2</jats:italic>).</jats:p>

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