Synthesis and thermoelectric properties of KyCo4Sb12

  • Y. Z. Pei
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • L. D. Chen
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • W. Zhang
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • X. Shi
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • S. Q. Bai
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • X. Y. Zhao
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • Z. G. Mei
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China
  • X. Y. Li
    Shanghai Institute of Ceramics State Key Laboratory of High Performance Ceramics and Superfine Microstructure, , Chinese Academy of Sciences, Shanghai 200050, China

書誌事項

公開日
2006-11-27
DOI
  • 10.1063/1.2397538
公開者
AIP Publishing

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説明

<jats:p>Polycrystalline K-filled CoSb3 are synthesized successfully. The uplimit for K filling is at least 0.45, being higher than those of either alkaline-earth (AE) or rare-earth (RE) metals but being in consistent with our earlier theoretical prediction. The measured transport properties (300–800K) show that K filling does not lower thermal conductivity much in comparison with AE or RE filling due to the relatively low mass of K atom. However, it improves electrical conductivity, retains large Seebeck coefficient, and leads to a reasonably good thermoelectric performance for the filled skutterudites. The maximum figure of merit ZT reaches 1 at 800K for K0.38Co4Sb12.</jats:p>

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