Photochemical Production of Interpenetrating Polymer Networks; Simultaneous Initiation of Radical and Cationic Polymerization Reactions

  • Jean Fouassier
    Department of Chemistry, University of Haute Alsace, Mulhouse 68057, France
  • Jacques Lalevée
    Department of Chemistry, University of Haute Alsace, Mulhouse 68057, France

書誌事項

公開日
2014-10-20
権利情報
  • https://creativecommons.org/licenses/by/4.0/
DOI
  • 10.3390/polym6102588
公開者
MDPI AG

説明

<jats:p>In this paper, we propose to review the ways to produce, through photopolymerization, interpenetrating polymer networks (IPN) based, e.g., on acrylate/epoxide or acrylate/vinylether blends and to outline the recent developments that allows a one-step procedure (concomitant radical/cationic polymerization), under air or in laminate, under various irradiation conditions (UV/visible/near IR; high/low intensity sources; monochromatic/polychromatic sources; household lamps/laser diodes/Light Emitting Diodes (LEDs)). The paper illustrates the encountered mechanisms and the polymerization profiles. A short survey on the available monomer systems and some brief examples of the attained final properties of the IPNs is also provided.</jats:p>

収録刊行物

  • Polymers

    Polymers 6 (10), 2588-2610, 2014-10-20

    MDPI AG

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