Layered metal uranyl phosphates. Retention of divalent ions by amine intercalates of uranyl phosphates
書誌事項
- 公開日
- 1986-01-01
- 権利情報
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- http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining
- DOI
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- 10.1139/v86-007
- 公開者
- Canadian Science Publishing
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説明
<jats:p> HUO<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>•4H<jats:sub>2</jats:sub>O (HUP) forms a laminar intercalate with butylamine, c = 29.30(5) Å, which accepts cationic metals in exchange for the n-butylammonium ions. Hydrated uranyl metal phosphates M(UO<jats:sub>2</jats:sub>PO<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub>•nH<jats:sub>2</jats:sub>O (M = Mn, Co, Ni, Cu, Zn, Cd) are obtained by ionic exchange and were studied by thermal analysis and X-ray diffraction. The tetragonal structures of all these product compounds are derived from HUP. The diffuse electronic reflectance spectra of every sample show characteristic [Formula: see text] absorption bands. In the spectra of the Co, Ni, and Cu phosphates there are other bands in the 500–800 nm zone compatible with their observed aquocation transitions. </jats:p>
収録刊行物
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- Canadian Journal of Chemistry
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Canadian Journal of Chemistry 64 (1), 30-34, 1986-01-01
Canadian Science Publishing
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詳細情報 詳細情報について
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- CRID
- 1363388844168184576
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- DOI
- 10.1139/v86-007
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- ISSN
- 14803291
- 00084042
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- データソース種別
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- Crossref
