Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer

  • M. Dell'Angela
    Universität Hamburg 1 Physics Department and Center for Free-Electron Laser Science, , 22607 Hamburg, Germany
  • T. Anniyev
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • M. Beye
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • R. Coffee
    SLAC National Accelerator Laboratory 5 LCLS, , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • A. Föhlisch
    Institute for Methods and Instrumentation in Synchrotron Radiation Research 4 , Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Wilhelm-Conrad-Röntgen Campus, Albert-Einstein-Str. 15, 12489 Berlin, Germany
  • J. Gladh
    Stockholm University 7 Department of Physics, AlbaNova University Center, , SE-10691 Stockholm, Sweden
  • S. Kaya
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • T. Katayama
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • O. Krupin
    SLAC National Accelerator Laboratory 8 Linac Coherent Light Source, , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • A. Nilsson
    Stockholm University 7 Department of Physics, AlbaNova University Center, , SE-10691 Stockholm, Sweden
  • D. Nordlund
    SLAC National Accelerator Laboratory 10 SSRL, , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • W. F. Schlotter
    SLAC National Accelerator Laboratory 8 Linac Coherent Light Source, , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • J. A. Sellberg
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • F. Sorgenfrei
    Universität Hamburg 1 Physics Department and Center for Free-Electron Laser Science, , 22607 Hamburg, Germany
  • J. J. Turner
    SLAC National Accelerator Laboratory 8 Linac Coherent Light Source, , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • H. Öström
    Stockholm University 7 Department of Physics, AlbaNova University Center, , SE-10691 Stockholm, Sweden
  • H. Ogasawara
    SUNCAT Center for Interface Science and Catalysis 3 , , 2575 Sand Hill Road, Menlo Park, California 94025, USA
  • M. Wolf
    Fritz-Haber Institute 11 , Max Planck Society, Faradayweg 4-6, D-14195 Berlin, Germany
  • W. Wurth
    Universität Hamburg 1 Physics Department and Center for Free-Electron Laser Science, , 22607 Hamburg, Germany

書誌事項

公開日
2015-03-01
権利情報
  • https://creativecommons.org/licenses/by/3.0/
  • https://creativecommons.org/licenses/by/3.0/
DOI
  • 10.1063/1.4914892
公開者
AIP Publishing

説明

<jats:p>Vacuum space charge induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.</jats:p>

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