Lipase active site covalent anchoring of Rh(NHC) catalysts: towards chemoselective artificial metalloenzymes
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- M. Basauri-Molina
- Organic Chemistry and Catalysis
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- C. F. Riemersma
- Organic Chemistry and Catalysis
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- M. A. Würdemann
- Organic Chemistry and Catalysis
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- H. Kleijn
- Organic Chemistry and Catalysis
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- R. J. M. Klein Gebbink
- Organic Chemistry and Catalysis
書誌事項
- 公開日
- 2015
- DOI
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- 10.1039/c4cc09700a
- 公開者
- Royal Society of Chemistry (RSC)
この論文をさがす
説明
<p>Artificial metallo-enzymes derived from active site-inhibited lipases show chemoselective reactivity in catalytic hydrogenations. Embedding of a non-natural metallic center leads to full and competitive selectivity.</p>
収録刊行物
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- Chemical Communications
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Chemical Communications 51 (31), 6792-6795, 2015
Royal Society of Chemistry (RSC)
