New Insights into Improving Rate Performance of Lithium‐Rich Cathode Material

  • Yongqing Wang
    National Institute of Advanced Industrial Science and Technology (AIST) Umezono 1‐1‐1 Tsukuba 305‐8568 Japan
  • Zhenzhong Yang
    Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China
  • Yumin Qian
    National Institute of Advanced Industrial Science and Technology (AIST) Umezono 1‐1‐1 Tsukuba 305‐8568 Japan
  • Lin Gu
    Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China
  • Haoshen Zhou
    National Institute of Advanced Industrial Science and Technology (AIST) Umezono 1‐1‐1 Tsukuba 305‐8568 Japan

書誌事項

公開日
2015-05-21
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201500956
公開者
Wiley

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説明

A Sn doping strategy is demonstrated to improve lithium diffusion kinetics by expanding the spacing of (003) planes without destroying the layered structure. A large (003) spacing will significantly decrease the energy barrier associated with lithium diffusion. Besides better rate capability, the Sn-doped material exhibits an unexpected much improved capacity above 3.0 V (vs Li(+) /Li), which is highly desired in future applications.

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