Syntheses and Structures of New Diruthenatetraborane Complexes Exhibiting Novel Modes of Coordination for a B<sub>2</sub>H<sub>5</sub>Fragment:  Phosphine-Complexed [(Cp*Ru)<sub>2</sub>(μ-H)(∥-μ-η<sup>4</sup>-B<sub>2</sub>H<sub>5</sub>)(PR<sub>3</sub>)] (PR<sub>3</sub>= PMe<sub>3</sub>, PMe<sub>2</sub>Ph) and Phosphido-Bridged<i>n</i><i>ido</i>-[(Cp*Ru)<sub>2</sub>(μ-PMe<sub>2</sub>)(⊥-μ-η<sup>4</sup>-B<sub>2</sub>H<sub>5</sub>)]<sup>1</sup>

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  • Lourdes N. Pangan
    Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan
  • Yasuro Kawano
    Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan
  • Mamoru Shimoi
    Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan

説明

Reaction of nido-[(Cp*Ru)2(μ-H)2(B3H7)] (1) with tertiary phosphines led to the degradation of the cluster framework and yielded [(Cp*Ru)2(μ-H)(∥-μ-η4-B2H5)(PR3)] (PR3 = PMe3 (2a); PMe2Ph (2b)). Th...

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  • Organometallics

    Organometallics 19 (26), 5575-5581, 2000-11-16

    American Chemical Society (ACS)

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